This may be caused by your allergetic to these chemical material . You can use them seperately to find which you are allergetic to ,the eyeline or the mascara . After you make it clear ,search the ingredients to see if there are prohibited parts. It is better to choose some hypoallergenic make-up .
It sounds like your are allergetic to eye makeup. You should stop wearing eye makeup for several days and see if it can get better. If it is really caused by eye makeup, you may switch to other brand which is hypoallergenic.